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Nynas has started to apply the MALDI-TOF measurement to determine molecular weight and to develop a greater understanding of mineral oils' chemical composition
Many Nynas customers appreciate the use of Matrix-Assisted Laser Desorption/Ionization – Time-of-Flight Mass Spectroscopy. "We're getting an increasing number of requests where knowing an estimated Mw is not enough – the absolute Mw or chain length distribution is required," says Dr. Markus Hoffmann, Chemical Industries Technical Manager at Nynas. "This is a method that can provide this information quickly and accurately, and even though this is not a standard test method yet, Nynas is a pioneer in the field."
The measurement of molecular weight (Mw) and molecular weight distribution is used to analyse and improve Nynas products. Until now the industry standard has been ASTM D2502, which is based on a calculation and provides information on the relative Mw. In contrast, MALDI-TOF is a direct measurement that gives an absolute value for the average molecular weight. It detects the molecular weight distribution as well. The applicable Mw range is 100 – 500,000 Da (compared to 250-700 Da for ASTM D2502).
"The MALDI spectra make it possible for us to get a better understanding of the molecular structures present in mineral oils; we can determine the exact chain length and degree of branching. Mineral oils contain a variety of structures, and until now the identification of these molecules has not really been possible since the other analytical techniques don't provide the information required," says Hoffmann. "Besides, it is important to know the Mw since some regulations specify certain Mw requirements and we need to make sure our products are compliant. The Mw is also an important factor for determining the risk of migration."
NYNÄSHAMN, SWEDEN, 9 MAY, 9:45 AM: Shift Manager Fredrik Svensson tops up the hot oil that is used to heat the oil supply in the HT2 hydrogenation plant ahead of the start-up after this spring’s turnaround at the refinery in Nynäshamn.Read more about Nynäshamn, Sweden, 9 May, 9:45 AM
Stina started at Nynas as Supply Chain planner EMEA after graduating from Linköping University with a Master of Science in Industrial Engineering and Management in 2007. She moved on to roles as Supply Chain Analyst, Contract Manager Supply Chain, and Planning Manager Supply Chain. Since December 2016, Stina has been Head of Supply Chain EMEA. Find out what's on her mind.Read more about The brains of Nynas: Stina Wiqvist