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Emulsions are used in metal working when cooling and lubrication are called for. The following review of factors governing the choice of emulsifier will, it is hoped, guide you through the jungle of different types.
In a previous article we studied HLB value and the importance of VGC in formulation. The present article deals with the response of different types of oil. Naphthenic-base oil needs less emulsifier than paraffin-base oil to give a stable emulsion.
A modern metalworking fluid can have more than 15 different components. These can be divided into the following groups:
To make this mixture soluble in water, a properly balanced emulsifier is needed. All additives interact with the emulsion system, and so the recipe has to be tailored to the exact requirements defined by oneself or the customer.
An emulsion consists of two or more insoluble phases. If the external phase is water and the internal one oil, the emulsion is called an oil in water (O/W). Milk, for example, is a typical O/W emulsion containing about 3.5% fat in a water phase, and butter is a W/O emulsion with about 20% water in the fat phase. The principle of the emulsifier is to have a polar tail for the water phase and a non-polar one for the fat phase. Through enrichment in the boundary zone between the phases, the emulsifier forms a transition between them.
Two kinds of emulsifiers are normally used in industry: ionic system and non-ionic systems. Mixtures of ionic and non-ionic systems occur. Co-emulsifiers and coupling agents are used for stabilising the system. The non-ionic emulsifiers cover the entire scale of HLB values and can be used in all products. Unfortunately they cost more than the ionic emulsifiers, which are the commonest type. There are great variations, and in deciding a recipe one has to choose between many different grades.
This type of emulsifier is used mostly in W/O systems and for balancing the ionic emulsifier in O/W formulas. On account of its stability and pH value, this is the type commonly used in metalworking oils.
There are two sorts of ionic emulsifier: anionic and cationic. The commonest types are anionic, soap and sulphonates being the commonest of all. Sulphonates and petroleum sulphonates have various molecular weights. A large proportion of sulphonates are alkyl sulphonates, by-products of alkyl benzene production. Sulphonated alkyl benzenes are the dominant product used for cleaning agents. The high pH values give protection against corrosion but they also cause environmental problems.
A coupling agent is soluble in oil and augments the solubility of the inner phase.
Alcohol is soluble in water and reduces the solubility of the outer phase. The solubility of the oil makes a difference to formulation. A highly soluble naphthenic-base oil needs less emulsifier than a paraffin-base oil. A more refined naphthenic-base oil also needs less emulsifier than one that is less refined. The charts show a stability test performed on four different emulsifiers. The difference in response between oils can be seen quite clearly. The smaller the layer of "cream" which settles on top of the mixture, the greater its stability will be. A naphthenic-base oil can give a stable emulsion with the addition of much less emulsifier than a paraffin-base oil. This can be seen best from diagrams 1-4.
| Emulsifier in the concentrate |
Ml Cream | |||
| 15% | 4 | 3.1 | 1.7 | 1.2 |
| 18% | 4 | 2.7 | 1.1 | |
| Base oil concentrate | 150 SUS p-base Separation |
NS 30 Separation |
T22 Stable |
H22 Stable |
Author
Gunnar Stang
T 22 is a mid viscosity hydrotreated naphthenic oil with excellent solvent power and very good low temperature properties.
Read more about NYNAS T 22 - NAPHTHENIC BASE OIL
Technical article
Low thickener content, good stability, flowability at low temperature and superior water spray-off give Nynas' BBT 28 base oil a clear advantage. Read more about Black is the new black
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Send an emailIlenia Bellotti
Customer Service Executive
Phone: +39-02-6070187
Mobile: +39-331-7341909
Send an emailmexico.orders@nynas.com
View all contactsRoberto Ortiz
General Manager / Sales Manager
Phone: +52-55-55363088
Mobile: +52-1-55-54141942
Send an emailAlicia Arciniega
Customer Service Coordinator
Phone: +52-55-55362847
Mobile: +52-1-55-54140712
Send an emailMartha Castro
Customer Service Coordinator
Phone: +52-55-55363088
Mobile: +52-1-55-54389448
Send an emailjason.wong@nynas.com
View all contactsShigeru Sano
General Manager / Sales Manager
Phone: +81-3-35603093
Mobile: +81-80-97108689
Send an emailKaruna Sadasivam
General Manager / Sales Manager
Phone: +971-4-3327125
Mobile: +971-50-5535786
Send an emailSibala Libish Kumar
Customer Service Executive
Phone: +971-4-3327125
Mobile: +971-56-1148325
Send an emailnynas.southafrica@nynas.com
View all contactsSamantha Moodley
Customer Service Executive
Phone: +27-10-5901052
Mobile: +27-82-5571589
Send an emailKaruna Sadasivam
General Manager / Sales Manager
Phone: +971-4-3327125
Mobile: +971-50-5535786
Send an emailSibala Libish Kumar
Customer Service Executive
Phone: +971-4-3327125
Mobile: +971-56-1148325
Send an emailLawrence Teo
Area Sales Manager Malaysia, Sri Lanka and Bangladesh
Phone: +65 6592 0957
Mobile: +65 87230248
Send an emailnordic.order@nynas.com
View all contactsMargareta Prevorsek
Customer Service Executive
Phone: +46-8-6021310
Mobile: +46-70-3148364
Send an emailKaruna Sadasivam
General Manager / Sales Manager
Phone: +971-4-3327125
Mobile: +971-50-5535786
Send an emailSibala Libish Kumar
Customer Service Executive
Phone: +971-4-3327125
Mobile: +971-56-1148325
Send an emailnynas.southafrica@nynas.com
View all contactsSamantha Moodley
Customer Service Executive
Phone: +27-10-5901052
Mobile: +27-82-5571589
Send an emailnynas.southafrica@nynas.com
View all contactsSamantha Moodley
Customer Service Executive
Phone: +27-10-5901052
Mobile: +27-82-5571589
Send an emailfrench.orders@nynas.com
View all contactsSheilo Mienandi
Customer Service Coordinator
Phone: +33-1-53349910
Mobile: +33-6-42009297
Send an emailnordic.order@nynas.com
View all contactsMargareta Prevorsek
Customer Service Executive
Phone: +46-8-6021310
Mobile: +46-70-3148364
Send an emailbenelux.orders@nynas.com
View all contactsLawrence Teo
Area Sales Manager Malaysia, Sri Lanka and Bangladesh
Phone: +65 6592 0957
Mobile: +65 87230248
Send an emailIlenia Bellotti
Customer Service Executive
Phone: +39-02-6070187
Mobile: +39-331-7341909
Send an emailnynas.southafrica@nynas.com
View all contactsSamantha Moodley
Customer Service Executive
Phone: +27-10-5901052
Mobile: +27-82-5571589
Send an emailnynas.southafrica@nynas.com
View all contactsSamantha Moodley
Customer Service Executive
Phone: +27-10-5901052
Mobile: +27-82-5571589
Send an emailLawrence Teo
Area Sales Manager Malaysia, Sri Lanka and Bangladesh
Phone: +65 6592 0957
Mobile: +65 87230248
Send an emailnynas.southafrica@nynas.com
View all contactsSamantha Moodley
Customer Service Executive
Phone: +27-10-5901052
Mobile: +27-82-5571589
Send an emailIlenia Bellotti
Customer Service Executive
Phone: +39-02-6070187
Mobile: +39-331-7341909
Send an emailnynas.southafrica@nynas.com
View all contactsSamantha Moodley
Customer Service Executive
Phone: +27-10-5901052
Mobile: +27-82-5571589
Send an emailmexico.orders@nynas.com
View all contactsRoberto Ortiz
General Manager / Sales Manager
Phone: +52-55-55363088
Mobile: +52-1-55-54141942
Send an emailAlicia Arciniega
Customer Service Coordinator
Phone: +52-55-55362847
Mobile: +52-1-55-54140712
Send an emailMartha Castro
Customer Service Coordinator
Phone: +52-55-55363088
Mobile: +52-1-55-54389448
Send an emailIlenia Bellotti
Customer Service Executive
Phone: +39-02-6070187
Mobile: +39-331-7341909
Send an emailfrench.orders@nynas.com
View all contactsSheilo Mienandi
Customer Service Coordinator
Phone: +33-1-53349910
Mobile: +33-6-42009297
Send an emailnynas.southafrica@nynas.com
View all contactsSamantha Moodley
Customer Service Executive
Phone: +27-10-5901052
Mobile: +27-82-5571589
Send an emailLawrence Teo
Area Sales Manager Malaysia, Sri Lanka and Bangladesh
Phone: +65 6592 0957
Mobile: +65 87230248
Send an emailnynas.southafrica@nynas.com
View all contactsSamantha Moodley
Customer Service Executive
Phone: +27-10-5901052
Mobile: +27-82-5571589
Send an emailbenelux.orders@nynas.com
View all contactssales.admin@molekulis.com.au
View all contactsAmanda Duncan
Customer Service Coordinator
Phone: +61-7-33906155
Mobile: +61-438-181676
Send an emailsales.admin@molekulis.com.au
View all contactsAmanda Duncan
Customer Service Coordinator
Phone: +61-7-33906155
Mobile: +61-438-181676
Send an emailnla.orders@nynas.com
View all contactsMarcela Tocelis
Sales Manager / Acting General Manager
Phone: +54-11-47770001
Mobile: +54-911-63817636
Send an emailAndrés Federuzzi
Sales Manager CMI & TYR
Phone: +54-11-47770001
Mobile: +54-911-31960832
Send an emailMartin Vergara
Customer Service Executive
Phone: +54-11-47770001
Mobile: +54-911-36974540
Send an emailJuan Pablo Pace
Customer Service Coordinator
Phone: +54-11-47770001
Mobile: +54-911-63557187
Send an emailnynas.southafrica@nynas.com
View all contactsSamantha Moodley
Customer Service Executive
Phone: +27-10-5901052
Mobile: +27-82-5571589
Send an emailSamantha Moodley
Customer Service Executive
Phone: +27-10-5901052
Mobile: +27-82-5571589
Send an emailAbigail Waller
General Manager / Sales Manager
Phone: +44-330-1239113
Mobile: +44-78-87510555
Send an emailnordic.order@nynas.com
View all contactsMargareta Prevorsek
Customer Service Executive
Phone: +46-8-6021310
Mobile: +46-70-3148364
Send an emailKaruna Sadasivam
General Manager / Sales Manager
Phone: +971-4-3327125
Mobile: +971-50-5535786
Send an emailSibala Libish Kumar
Customer Service Executive
Phone: +971-4-3327125
Mobile: +971-56-1148325
Send an emailKaruna Sadasivam
General Manager / Sales Manager
Phone: +971-4-3327125
Mobile: +971-50-5535786
Send an emailSibala Libish Kumar
Customer Service Executive
Phone: +971-4-3327125
Mobile: +971-56-1148325
Send an emailnla.orders@nynas.com
View all contactsMarcela Tocelis
Sales Manager / Acting General Manager
Phone: +54-11-47770001
Mobile: +54-911-63817636
Send an emailAndrés Federuzzi
Sales Manager CMI & TYR
Phone: +54-11-47770001
Mobile: +54-911-31960832
Send an emailMartin Vergara
Customer Service Executive
Phone: +54-11-47770001
Mobile: +54-911-36974540
Send an emailJuan Pablo Pace
Customer Service Coordinator
Phone: +54-11-47770001
Mobile: +54-911-63557187
Send an emailsales.admin@molekulis.com.au
View all contactsAmanda Duncan
Customer Service Coordinator
Phone: +61-7-33906155
Mobile: +61-438-181676
Send an emailnla.orders@nynas.com
View all contactsMarcela Tocelis
Sales Manager / Acting General Manager
Phone: +54-11-47770001
Mobile: +54-911-63817636
Send an emailAndrés Federuzzi
Sales Manager CMI & TYR
Phone: +54-11-47770001
Mobile: +54-911-31960832
Send an emailMartin Vergara
Customer Service Executive
Phone: +54-11-47770001
Mobile: +54-911-36974540
Send an emailJuan Pablo Pace
Customer Service Coordinator
Phone: +54-11-47770001
Mobile: +54-911-63557187
Send an emailnla.orders@nynas.com
View all contactsMarcela Tocelis
Sales Manager / Acting General Manager
Phone: +54-11-47770001
Mobile: +54-911-63817636
Send an emailAndrés Federuzzi
Sales Manager CMI & TYR
Phone: +54-11-47770001
Mobile: +54-911-31960832
Send an emailMartin Vergara
Customer Service Executive
Phone: +54-11-47770001
Mobile: +54-911-36974540
Send an emailJuan Pablo Pace
Customer Service Coordinator
Phone: +54-11-47770001
Mobile: +54-911-63557187
Send an emailLawrence Teo
Area Sales Manager Malaysia, Sri Lanka and Bangladesh
Phone: +65 6592 0957
Mobile: +65 87230248
Send an emailpoland.orders@nynas.com
View all contactsEdyta Bartosz
Customer Service Coordinator
Phone: +48-32-2327930
Mobile: +48-669-696116
Send an emailAldona Dziedzic
Customer Service Executive
Phone: +48-32-2327410
Mobile: +48-605-333476
Send an emailnynas.pedidos@nynas.com
View all contactsMyriam Picado
General Manager / Sales Manager
Phone: +34-917-021875
Mobile: +34-670-335355
Send an emailJose Luis Maceda
Customer Service Coordinator
Phone: +34-917 021 875
Mobile: +34-608-051706
Send an emailGloria Villaverde Parrado
Customer Service Executive
Phone: +34-917-021875
Mobile: +34-610-552947
Send an emailnla.orders@nynas.com
View all contactsMarcela Tocelis
Sales Manager / Acting General Manager
Phone: +54-11-47770001
Mobile: +54-911-63817636
Send an emailAndrés Federuzzi
Sales Manager CMI & TYR
Phone: +54-11-47770001
Mobile: +54-911-31960832
Send an emailMartin Vergara
Customer Service Executive
Phone: +54-11-47770001
Mobile: +54-911-36974540
Send an emailJuan Pablo Pace
Customer Service Coordinator
Phone: +54-11-47770001
Mobile: +54-911-63557187
Send an emailKaruna Sadasivam
General Manager / Sales Manager
Phone: +971-4-3327125
Mobile: +971-50-5535786
Send an emailSibala Libish Kumar
Customer Service Executive
Phone: +971-4-3327125
Mobile: +971-56-1148325
Send an emailaustria.orders@nynas.com
View all contactsElisabeth Treiber
Customer Service Executive
Phone: +43-316-73460010
Mobile: +43-664-2046516
Send an emailSabine Langmuller
Customer Service Coordinator
Phone: +43 316 734 600 20
Mobile: +43 699 100 47 707
Send an emailnynas.southafrica@nynas.com
View all contactsSamantha Moodley
Customer Service Executive
Phone: +27-10-5901052
Mobile: +27-82-5571589
Send an emailnynas.southafrica@nynas.com
View all contactsSamantha Moodley
Customer Service Executive
Phone: +27-10-5901052
Mobile: +27-82-5571589
Send an emailKaruna Sadasivam
General Manager / Sales Manager
Phone: +971-4-3327125
Mobile: +971-50-5535786
Send an emailSibala Libish Kumar
Customer Service Executive
Phone: +971-4-3327125
Mobile: +971-56-1148325
Send an emailAbigail Waller
General Manager / Sales Manager
Phone: +44-330-1239113
Mobile: +44-78-87510555
Send an emailnynas.southafrica@nynas.com
View all contactsSamantha Moodley
Customer Service Executive
Phone: +27-10-5901052
Mobile: +27-82-5571589
Send an emailIlenia Bellotti
Customer Service Executive
Phone: +39-02-6070187
Mobile: +39-331-7341909
Send an emailnynas.southafrica@nynas.com
View all contactsSamantha Moodley
Customer Service Executive
Phone: +27-10-5901052
Mobile: +27-82-5571589
Send an emailnynas.southafrica@nynas.com
View all contactsSamantha Moodley
Customer Service Executive
Phone: +27-10-5901052
Mobile: +27-82-5571589
Send an emailsingapore.orders@nynas.com
View all contactsLawrence Teo
Area Sales Manager Malaysia, Sri Lanka and Bangladesh
Phone: +65 6592 0957
Mobile: +65 87230248
Send an emailaustria.orders@nynas.com
View all contactsElisabeth Treiber
Customer Service Executive
Phone: +43-316-73460010
Mobile: +43-664-2046516
Send an emailSabine Langmuller
Customer Service Coordinator
Phone: +43 316 734 600 20
Mobile: +43 699 100 47 707
Send an emailaustria.orders@nynas.com
View all contactsElisabeth Treiber
Customer Service Executive
Phone: +43-316-73460010
Mobile: +43-664-2046516
Send an emailSabine Langmuller
Customer Service Coordinator
Phone: +43 316 734 600 20
Mobile: +43 699 100 47 707
Send an emailnynas.southafrica@nynas.com
View all contactsSamantha Moodley
Customer Service Executive
Phone: +27-10-5901052
Mobile: +27-82-5571589
Send an emailnynas.southafrica@nynas.com
View all contactsSamantha Moodley
Customer Service Executive
Phone: +27-10-5901052
Mobile: +27-82-5571589
Send an emailLawrence Teo
Area Sales Manager Malaysia, Sri Lanka and Bangladesh
Phone: +65 6592 0957
Mobile: +65 87230248
Send an emailsales.admin.brisbane@nynas.com
View all contactsAmanda Duncan
Customer Service Coordinator
Phone: +61-7-33906155
Mobile: +61-438-181676
Send an emailnynas.pedidos@nynas.com
View all contactsMyriam Picado
General Manager / Sales Manager
Phone: +34-917-021875
Mobile: +34-670-335355
Send an emailJose Luis Maceda
Customer Service Coordinator
Phone: +34-917 021 875
Mobile: +34-608-051706
Send an emailGloria Villaverde Parrado
Customer Service Executive
Phone: +34-917-021875
Mobile: +34-610-552947
Send an emailLawrence Teo
Area Sales Manager Malaysia, Sri Lanka and Bangladesh
Phone: +65 6592 0957
Mobile: +65 87230248
Send an emailKaruna Sadasivam
General Manager / Sales Manager
Phone: +971-4-3327125
Mobile: +971-50-5535786
Send an emailSibala Libish Kumar
Customer Service Executive
Phone: +971-4-3327125
Mobile: +971-56-1148325
Send an emailnla.orders@nynas.com
View all contactsMarcela Tocelis
Sales Manager / Acting General Manager
Phone: +54-11-47770001
Mobile: +54-911-63817636
Send an emailAndrés Federuzzi
Sales Manager CMI & TYR
Phone: +54-11-47770001
Mobile: +54-911-31960832
Send an emailMartin Vergara
Customer Service Executive
Phone: +54-11-47770001
Mobile: +54-911-36974540
Send an emailJuan Pablo Pace
Customer Service Coordinator
Phone: +54-11-47770001
Mobile: +54-911-63557187
Send an emailnynas.southafrica@nynas.com
View all contactsSamantha Moodley
Customer Service Executive
Phone: +27-10-5901052
Mobile: +27-82-5571589
Send an emailnordic.order@nynas.com
View all contactsMargareta Prevorsek
Customer Service Executive
Phone: +46-8-6021310
Mobile: +46-70-3148364
Send an emailfrench.orders@nynas.com
View all contactsSheilo Mienandi
Customer Service Coordinator
Phone: +33-1-53349910
Mobile: +33-6-42009297
Send an emailKaruna Sadasivam
General Manager / Sales Manager
Phone: +971-4-3327125
Mobile: +971-50-5535786
Send an emailSibala Libish Kumar
Customer Service Executive
Phone: +971-4-3327125
Mobile: +971-56-1148325
Send an emailLawrence Teo
Area Sales Manager Malaysia, Sri Lanka and Bangladesh
Phone: +65 6592 0957
Mobile: +65 87230248
Send an email