Testing oils for TPE

Successfully marrying the properties of plastics and rubbers, thermoplastic elastomers (TPE) are used in everything from car dashboards to toothbrushes and the soles of our shoes. In a recent study, Nynas researchers were able to confirm the high performance of the company’s highly refined oils in TPE materials.

Dr Kamyar Alavi

Senior Technical Advisor
Nynas AB

"Thermoplastic elastomers have the desirable properties of elastomeric materials, such as the tactile feel, damping, and low temperature properties. But unlike common rubber material – which once vulcanised into a certain shape cannot be reshaped – TPE materials keep the melt processing characteristics of plastics, enabling them to be remoulded. This offers higher flexibility for both processing and recycling,” explains Dr Kamyar Alavi, Senior Specialist, Nynas.

Found in numerous applications and everyday goods, TPE materials are formulated compounds containing a TPE polymer and other components such as a polyolefin, filler, antioxidative additives and a process oil. The oil plays a vital role, as it is not uncommon for the oil loading to reach as high a level as that of the main polymer, the TPE.

“Many TPE materials are used in high-end and light-colour applications, so the ageing and colour stability of the products are of special importance. This, in combination with the high amount of oil, means that the colour stability of the oil is a key parameter for the overall performance,” says Kamyar Alavi.

To evaluate the performance of highly refined oils in TPE materials, Kamyar Alavi and his colleagues Tommie Ibert and Patrik Salomonsson recently conducted a comparative study. The performance of Nynas process oils NYFLEX® 223 and NYPAR® 330, as well as performance- optimised (additivated) versions of these oils, DP 223 and DP 330, were assessed alongside commonly used paraffinic TPE process oils.

“Since many of the final products are exposed to light, one of the most important aims of the project was to study the impact of the oil on the UV-ageing of the compound. To this end, we tracked the changes of key compound properties as a function of UV exposure time,” explains Alavi.

The results, shown in Figure 1, indicate that most ageing occurs in the early periods of exposure reaching almost maximum level after 168 h. Compounds with NYFLEX 223 perform at least at the same level as the paraffinic Gr I oils, SN500 and SN600. The enhanced naphthenic oil DP 223 shows significant improvement in colour getting closer to that seen in NYPAR 330 compounds, while DP 330 performs at an almost identical level as the paraffinic medical white oil (P-MWO).

Structurally, TPEs comprise thermoplastic hard blocks, interconnected by elastomeric mid-blocks. One of the most important TPE materials is the so called Styrenic Block Copolymers (SBC or TPS). In these, the thermoplastic block is made of polystyrene interconnected by the elastomeric mid-blocks such as butadiene or isoprene rubber. The role of the oil is to offer optimum plastification of the rubbery phase without inadequate interference with the hard (styrenic) phase.

Further reading

Better tyre recipes

Multivariate analysis tools can help Nynas and its customers to optimise the formulation of tyre rubber compounds, Nynas researchers conclude after some initial tests.

Increased Sustainability: Tyre Rubbers with Raw Materials from Renewable Resources

Tyre industry’s strive to reach higher levels of sustainability has been gaining strength in the past recent years, which among other things is reflected in the explicit sustainability targets communicated from several producers. The solution is multifaceted, one of the routes to stand up to the challenge has been the introduction of alternative raw materials for the production of tyres.

Performance testing in real tyres

Nynas is stepping up its commitment to sustainability by bringing its tyre testing from the lab to the field – testing the performance of its biobased NYTEX® BIO 6200 oil in real tyres.

THERE IS MORE TO US THAN THIS

We are delighted you are interested in our products. If you have any questions about our products and services, get in touch with your local Nynas contact. Besides top quality oils, we offer a wide range of services, including rapid delivery worldwide, training, seminars and much more. All you have to do is ask.

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Marcela Tocelis

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David Barnett

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General Manager Germany & Austria

Lars Fischer

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Sales Executive Process Oils

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Elena Campmann

Customer Service Specialist – Global Processes and Development Lead

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Selina Walther

Customer Service Coordinator

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Michelle Krämer

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Marcela Tocelis

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Marcela Tocelis

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Global Customer Service Specialist & Project lead

 Sameen Kadli

Sameen Kadli

Sales Manager

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Shoeb Ahmed

Customer Service Coordinator

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Sibala Libish Kumar

Global Customer Service Specialist & Project lead

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Global Customer Service Specialist & Project lead

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Lee Anne Williams

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Lee Anne Williams

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Samantha Moodley

Customer Service Executive

Lee Anne Williams

Lee Anne Williams

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Daniele Frustagli

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David Barnett

David Barnett

General Manager

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Sales Manager, Bitumen Western Europe

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Global Customer Service Specialist & Project lead

 Sameen Kadli

Sameen Kadli

Sales Manager

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Customer Service Coordinator

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Global Customer Service Specialist & Project lead

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Global Customer Service Specialist & Project lead

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David Barnett

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Samantha Moodley

Customer Service Executive

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Lee Anne Williams

Customer Service Coordinator

David Barnett

David Barnett

General Manager

 Samantha Moodley

Samantha Moodley

Customer Service Executive

Lee Anne Williams

Lee Anne Williams

Customer Service Coordinator

 Sameen Kadli

Sameen Kadli

Sales Manager

Shoeb Ahmed

Shoeb Ahmed

Customer Service Coordinator

 Sibala Libish Kumar

Sibala Libish Kumar

Global Customer Service Specialist & Project lead

David Barnett

David Barnett

General Manager

 Samantha Moodley

Samantha Moodley

Customer Service Executive

Lee Anne Williams

Lee Anne Williams

Customer Service Coordinator

Daniele Frustagli

General Manager

David Barnett

David Barnett

General Manager

 Samantha Moodley

Samantha Moodley

Customer Service Executive

Lee Anne Williams

Lee Anne Williams

Customer Service Coordinator

David Barnett

David Barnett

General Manager

 Samantha Moodley

Samantha Moodley

Customer Service Executive

Lee Anne Williams

Lee Anne Williams

Customer Service Coordinator

Lawrence Teo

Lawrence Teo

Area Sales Manager

 Georgina Ng

Georgina Ng

Customer Service Executive

Alistair Meyer

Alistair Meyer

Regional Director

 Ovidiu Nan

Ovidiu Nan

General Manager

Sabine Langmuller

Sabine Langmuller

Customer Service Coordinator

 Ovidiu Nan

Ovidiu Nan

General Manager

Sabine Langmuller

Sabine Langmuller

Customer Service Coordinator

David Barnett

David Barnett

General Manager

 Samantha Moodley

Samantha Moodley

Customer Service Executive

Lee Anne Williams

Lee Anne Williams

Customer Service Coordinator

David Barnett

David Barnett

General Manager

 Samantha Moodley

Samantha Moodley

Customer Service Executive

Lee Anne Williams

Lee Anne Williams

Customer Service Coordinator

Lawrence Teo

Lawrence Teo

Area Sales Manager

 Georgina Ng

Georgina Ng

Customer Service Executive

Alistair Meyer

Alistair Meyer

Regional Director

Lawrence Teo

Lawrence Teo

Area Sales Manager

 Georgina Ng

Georgina Ng

Customer Service Executive

Alistair Meyer

Alistair Meyer

Regional Director

 Myriam Picado

Myriam Picado

General Manager / Sales Manager

 Juan Jiménez

Juan Jiménez

Sales Executive

 Jose Luis Maceda

Jose Luis Maceda

Customer Service Coordinator

 Gloria Villaverde Parrado

Gloria Villaverde Parrado

Customer Service Executive

Lawrence Teo

Lawrence Teo

Area Sales Manager

 Georgina Ng

Georgina Ng

Customer Service Executive

Alistair Meyer

Alistair Meyer

Regional Director

 Sameen Kadli

Sameen Kadli

Sales Manager

Shoeb Ahmed

Shoeb Ahmed

Customer Service Coordinator

 Sibala Libish Kumar

Sibala Libish Kumar

Global Customer Service Specialist & Project lead

 Marcela Tocelis

Marcela Tocelis

Sales Manager / Acting General Manager

 Martin Vergara

Martin Vergara

Customer Service Executive

 Juan Pablo Pace

Juan Pablo Pace

Customer Service Coordinator

David Barnett

David Barnett

General Manager

 Samantha Moodley

Samantha Moodley

Customer Service Executive

Lee Anne Williams

Lee Anne Williams

Customer Service Coordinator

 Henrik Marits

Henrik Marits

Sales Manager

Viktor Risendal

Sales Executive Nordic

Margita Thorén

Customer Service Coordinator

Eric Alfosea

Eric Alfosea

Sales Manager France

 Stéphanie Ly

Stéphanie Ly

Customer Service Executive

 Christine Le Garrec

Christine Le Garrec

Customer Service Coordinator

Sheilo Mienandi

Sheilo Mienandi

Customer Service Coordinator

 Sameen Kadli

Sameen Kadli

Sales Manager

Shoeb Ahmed

Shoeb Ahmed

Customer Service Coordinator

 Sibala Libish Kumar

Sibala Libish Kumar

Global Customer Service Specialist & Project lead

Lawrence Teo

Lawrence Teo

Area Sales Manager

 Georgina Ng

Georgina Ng

Customer Service Executive

Alistair Meyer

Alistair Meyer

Regional Director

David Barnett

David Barnett

General Manager

 Samantha Moodley

Samantha Moodley

Customer Service Executive

Lee Anne Williams

Lee Anne Williams

Customer Service Coordinator

Lawrence Teo

Lawrence Teo

Area Sales Manager

 Georgina Ng

Georgina Ng

Customer Service Executive

Alistair Meyer

Alistair Meyer

Regional Director

David Barnett

David Barnett

General Manager

 Samantha Moodley

Samantha Moodley

Customer Service Executive

Lee Anne Williams

Lee Anne Williams

Customer Service Coordinator

 Marcela Tocelis

Marcela Tocelis

Sales Manager / Acting General Manager

 Martin Vergara

Martin Vergara

Customer Service Executive

 Juan Pablo Pace

Juan Pablo Pace

Customer Service Coordinator

Eric Alfosea

Eric Alfosea

Sales Manager France

 Stéphanie Ly

Stéphanie Ly

Customer Service Executive

 Christine Le Garrec

Christine Le Garrec

Customer Service Coordinator

Sheilo Mienandi

Sheilo Mienandi

Customer Service Coordinator

Emil Cuculayef

Emil Cuculayef

Sales Manager

 Banu Kibar

Banu Kibar

Customer Service Executive

Cagatay Gürol

Cagatay Gürol

Customer Service Coordinator

David Barnett

David Barnett

General Manager

 Samantha Moodley

Samantha Moodley

Customer Service Executive

Lee Anne Williams

Lee Anne Williams

Customer Service Coordinator

 Sameen Kadli

Sameen Kadli

Sales Manager

Shoeb Ahmed

Shoeb Ahmed

Customer Service Coordinator

 Sibala Libish Kumar

Sibala Libish Kumar

Global Customer Service Specialist & Project lead

 Marcela Tocelis

Marcela Tocelis

Sales Manager / Acting General Manager

 Martin Vergara

Martin Vergara

Customer Service Executive

 Juan Pablo Pace

Juan Pablo Pace

Customer Service Coordinator

 Marcela Tocelis

Marcela Tocelis

Sales Manager / Acting General Manager

 Marcela Tocelis

Marcela Tocelis

Sales Manager / Acting General Manager

 Martin Vergara

Martin Vergara

Customer Service Executive

 Juan Pablo Pace

Juan Pablo Pace

Customer Service Coordinator

Lawrence Teo

Lawrence Teo

Area Sales Manager

 Georgina Ng

Georgina Ng

Customer Service Executive

Alistair Meyer

Alistair Meyer

Regional Director

David Barnett

David Barnett

General Manager

 Samantha Moodley

Samantha Moodley

Customer Service Executive

Lee Anne Williams

Lee Anne Williams

Customer Service Coordinator

David Barnett

David Barnett

General Manager

 Samantha Moodley

Samantha Moodley

Customer Service Executive

Lee Anne Williams

Lee Anne Williams

Customer Service Coordinator