Assisting an agent

Compatible with all sorts of rubber, naphthenic oil facilitates the dispersion of insoluble sulfur, the vulcanising agent used in the production of tyre rubber. Anna Eriksson explains how this helps improve the quality of the final rubber.

Anna Eriksson

Technical Manager
Nynas AB

Compatible with all sorts of rubber, naphthenic oil facilitates the dispersion of insoluble sulfur, the vulcanising agent used in the production of tyre rubber. Anna Eriksson explains how this helps improve the quality of the final rubber.

Sulfur is used as a cross-linking agent during the vulcanisation of rubber, and although ordinary sulfur is the most commonly used vulcanising agent, many producers, especially those that make tyre rubber, prefer to use insoluble sulfur.

“This is because insoluble sulfur avoids issues related to migration,” explains Anna Eriksson, Technical Manager, Nynas Naphthenics.

Migration or ‘sulfur bloom’ refers to the crystallisation of sulfur on the surface of rubber. This occurs because normal sulfur is soluble and will dissolve within the rubber. When the rubber is heated during the vulcanisation process the sulfur can migrate to the surface, where it will crystallise as the rubber cools. For tyre rubber and other high-end rubber products, sulfur bloom will cause problems in subsequent processing steps.

Arranged in rings of eight sulfur atoms, normal soluble sulfur is made insoluble in a process that sees it first heated and then quickly cooled. This fuses the S8 rings into long polymeric, and insoluble, chains. However, insoluble sulfur tends to revert back to the soluble non-polymeric form quite quickly, unless it is kept dispersed in an oil.

“Naphthenic oil is particularly suitable for this purpose as it efficiently prevents reversion back to the soluble form. At the same time, it also enables the curing agent, in this case insoluble sulfur, to be properly incorporated into a wide selection of rubber. Naphthenic oil is highly compatible with all sorts of rubber compounds, facilitating the dispersion of sulfur and ensuring a good cross-linking density in the final rubber goods,” explains Anna Eriksson.

The most commonly used oil has a viscosity around 22 cSt (at 40°C), and the amount of oil varies between 10 and 40 percent. Offering high compatibility with a broad range of elastomers, high solvent power, and non-staining behaviour, NYTEX® 810 is widely used by producers.

Further reading

Solving the puzzle of Solubility

Solubility is a key focus point for Nynas’ researchers as it is one of the main characteristics to consider when choosing process oil for different applications. However, as the established methods for measuring the dissolving capability of oil are not ideal, the researchers are looking for alternatives.

Perfecting purification

In a study aimed at finding the most effective purifying oil for crude titanium tetrachloride, Nynas’ researchers obtained near perfection from one mineral oil and promising results from a hybrid biogenic oil.

Solvency offers great solutions

High solvent power is the secret of the success of naphthenic oils in chemical applications. Anna Eriksson, Technical Manager, Nynas Naphthenics, offers a couple of examples that explain why.

THERE IS MORE TO US THAN THIS

We are delighted you are interested in our products. If you have any questions about our products and services, get in touch with your local Nynas contact. Besides top quality oils, we offer a wide range of services, including rapid delivery worldwide, training, seminars and much more. All you have to do is ask.

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Global Customer Service Specialist & Project lead

 Marcela Tocelis

Marcela Tocelis

Sales Manager / Acting General Manager

 Martin Vergara

Martin Vergara

Customer Service Executive

 Juan Pablo Pace

Juan Pablo Pace

Customer Service Coordinator

 Marcela Tocelis

Marcela Tocelis

Sales Manager / Acting General Manager

 Marcela Tocelis

Marcela Tocelis

Sales Manager / Acting General Manager

 Martin Vergara

Martin Vergara

Customer Service Executive

 Juan Pablo Pace

Juan Pablo Pace

Customer Service Coordinator

Lawrence Teo

Lawrence Teo

Area Sales Manager

 Georgina Ng

Georgina Ng

Customer Service Executive

Alistair Meyer

Alistair Meyer

Regional Director

David Barnett

David Barnett

General Manager

 Samantha Moodley

Samantha Moodley

Customer Service Executive

Lee Anne Williams

Lee Anne Williams

Customer Service Coordinator

David Barnett

David Barnett

General Manager

 Samantha Moodley

Samantha Moodley

Customer Service Executive

Lee Anne Williams

Lee Anne Williams

Customer Service Coordinator