Solvency offers great solutions

High solvent power is the secret of the success of naphthenic oils in chemical applications. Anna Eriksson, Technical Manager, Nynas Naphthenics, offers a couple of examples that explain why.

Anna Eriksson

Technical Manager
Nynas AB 

The excellent solvency performance of naphthenic process oils gives Nynas a competitive edge in many of the around 20 different application areas the company serves within the chemical industry segment.

“Solvent power is important in many different applications. One example is the dissolving of resins in printing ink formulations. We have tested Nynas naphthenic oils of varying viscosity alongside Group I paraffinic oil of matching viscosity and found clear correlations to their respective solvent power,” says Anna Eriksson.

The screening was conducted using cloud point evaluation. The cloud point is the temperature at which dissolved solids are no longer completely soluble in a fluid. The solvent power is responsible for keeping the resin in solution.

“The cloud point can also be used to indicate the time and energy needed for the dissolution, and this can be used to assess the economic and environmental impact of using naphthenic versus paraffinic oil. The high solvent power of naphthenic oil makes it a clear winner.”

Another example of the importance of solvency can be found in antifoam production.

“When an antifoam is prepared, the active component must be dissolved and kept in solution until it is needed. Comparative studies clearly show that oils with higher solvent power facilitate the dissolution of active ingredients such as those used in antifoams,” says Anna Eriksson.

The solvent power plays an important role in all production processes where oil is used. High solvent power offers formulators flexibility to use a wide range of raw materials, higher loading of active ingredients or additives, and shorter process times.

In a comparative study, 10 % of phenolic rosin ester resin in oil was heated until fully dissolved, then allowed to cool until precipitation (a second phase) occurred. The high solvent power of the naphthenic oil has a great impact.

  • The solvent power of an oil is dependent on its dispersive forces. These, in turn, depend on the electron density which depends on the oil’s molecular structure and bond type.
  • Aromatic (unsaturated cyclic) hydrocarbons (a) display very powerful dispersive forces, due to very high electron density. However, the unsaturation can also promote unwanted reactions.
  • Stable and non-harmful, naphthenic (saturated cyclic) structures (b) have stronger dispersive forces than paraffinic (saturated straight) structures (c).
  • The stronger the dispersive forces, the higher the solvent power.

Further reading

Solving the puzzle of Solubility

Solubility is a key focus point for Nynas’ researchers as it is one of the main characteristics to consider when choosing process oil for different applications. However, as the established methods for measuring the dissolving capability of oil are not ideal, the researchers are looking for alternatives.

Fertile formulations

Having established in-house coating and testing of solid fertiliser, a Nynas researcher finds that naphthenic process oils offer coating formulations capable of reducing both dust and caking issues.

Assisting an agent

Compatible with all sorts of rubber, naphthenic oil facilitates the dispersion of insoluble sulfur, the vulcanising agent used in the production of tyre rubber. Anna Eriksson explains how this helps improve the quality of the final rubber.

THERE IS MORE TO US THAN THIS

We are delighted you are interested in our products. If you have any questions about our products and services, get in touch with your local Nynas contact. Besides top quality oils, we offer a wide range of services, including rapid delivery worldwide, training, seminars and much more. All you have to do is ask.

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David Barnett

General Manager

 Samantha Moodley

Samantha Moodley

Customer Service Executive

Lee Anne Williams

Lee Anne Williams

Customer Service Coordinator

 Sameen Kadli

Sameen Kadli

Sales Manager

Shoeb Ahmed

Shoeb Ahmed

Customer Service Coordinator

 Sibala Libish Kumar

Sibala Libish Kumar

Global Customer Service Specialist & Project lead

 Marcela Tocelis

Marcela Tocelis

Sales Manager / Acting General Manager

 Martin Vergara

Martin Vergara

Customer Service Executive

 Juan Pablo Pace

Juan Pablo Pace

Customer Service Coordinator

 Marcela Tocelis

Marcela Tocelis

Sales Manager / Acting General Manager

 Marcela Tocelis

Marcela Tocelis

Sales Manager / Acting General Manager

 Martin Vergara

Martin Vergara

Customer Service Executive

 Juan Pablo Pace

Juan Pablo Pace

Customer Service Coordinator

Lawrence Teo

Lawrence Teo

Area Sales Manager

 Georgina Ng

Georgina Ng

Customer Service Executive

Alistair Meyer

Alistair Meyer

Regional Director

David Barnett

David Barnett

General Manager

 Samantha Moodley

Samantha Moodley

Customer Service Executive

Lee Anne Williams

Lee Anne Williams

Customer Service Coordinator

David Barnett

David Barnett

General Manager

 Samantha Moodley

Samantha Moodley

Customer Service Executive

Lee Anne Williams

Lee Anne Williams

Customer Service Coordinator