Fertile formulations

Having established in-house coating and testing of solid fertiliser, a Nynas researcher finds that naphthenic process oils offer coating formulations capable of reducing both dust and caking issues.

Emma Öberg

Development Engineer, Nynas

She joined Nynas in 2016.

Being hygroscopic, solid fertiliser tends to absorb moisture, leading to caking and handling issues. The fertiliser can also create dust, a work environment hazard. However, both these issues can be addressed by coating the fertiliser, and process oil can be used either neat or in formulated coatings, also containing wax and hydrophobic amines.

Unfortunately, there are only a few standard methods for coating fertiliser or for relevant testing of coated solid fertiliser on a lab scale, so in order to study how their naphthenic process oil products perform in this application, Nynas had to develop their own in-house coating and testing equipment and procedures.

“Fertiliser producers or their coating formulators often use their own internal methods, but we wanted to be able to prepare and test fertiliser coatings in our own lab,” explains Emma Öberg, Development Engineer at Nynas.

Having set up a testbed for the comparative evaluation of different oils, she was able to determine that naphthenic process oils offer benefits and can be used to replace diminishing volumes of Group I oils in this application. However, Nynas products also showed performance advantages compared with Group II oils.

“The study shows that naphthenic process oils keep amines in solution at lower temperatures than Group I or Group II oils. This allows an anti- caking coating to be sprayed at lower temperatures, enabling cost reductions for processors,” says Emma Öberg.

Amine and oil blends prepared with the naphthenic mineral oil NYTEX® 820 had a lower cloud point compared with Group I and Group II oils of the same viscosity, indicating higher solvent power. Figure 1. shows the correlation between the cloud point for amine and oil blends and the respective oil’s aniline point.

The study also looked at the anti-dust performance of various Nynas products. Figure 2. shows the dusting tendency of untreated and oil coated multi-nutrient NPK (Nitrogen, Phosphorous and Potassium) fertiliser. The results indicate that dust levels can be significantly reduced by coating the fertiliser with a naphthenic process oil.

“Testing different oils showed that the addition of Nynas process oil to NPK fertiliser reduced dust by 50 percent,” says Emma Öberg.

Coatings Checklist

The results of Nynas’ fertiliser coatings study can be summarised in a checklist for coatings formulators or fertiliser companies.

  • Naphthenic process oils have higher solvency and will keep amines in solution at lower temperatures than Group I and Group II oils.
  • A higher nitrogen content will typically make the fertiliser cake more easily.
  • Consider the fertiliser’s Critical Relative Humidity (CRH) value when estimating which type of coating is needed.
  • Choose oils of low colour to coat Calcium Ammonium Nitrate (CAN) if it is important to keep its white colour intact.
  • Ammonium sulfate (AS) has lower caking tendency, so will need mainly anti-dust coating.

Figure 1. Correlation between cloud point for amine and oil blends and aniline point of the oil. Oil aniline point: Group I (115 cSt at 40 °C, AP 116°C), Group II (106 cSt at 40 °C, AP 126°C), NYTEX® 820 (110 cSt at 40 °C, AP 86°C).

Figure 2. The dusting tendency of NPK fertiliser can be significantly reduced by coating with a naphthenic process oil.

Further reading

Nappy change no problem

Disposable nappies are changing, but not to the naked eye. The change is hidden in the polymers that make up the adhesives in their non-woven materials. Will Nynas specialty oils work in the ever-changing adhesives market?

Sealing deal for Sealants

Producers of silicone sealants need look no further. Nynas has developed a range of specially designed silicone fluid alternatives that are cost-efficient and offer the right balance in formulations between viscosity, colour stability and volatility.

Naphthenic oil improves artificial fertilisers

The use of fertilisers around the world to boost agricultural production is both vital and constantly under critical scrutiny. Developing products that provide optimum benefits both economically and from an ecological viewpoint is an important challenge for the artificial fertiliser producer. Very small quantities of oil are employed in the production of fertilisers. The market demands optimal products and every link of the chain must be taken into consideration, including the properties of the oil being used.

THERE IS MORE TO US THAN THIS

We are delighted you are interested in our products. If you have any questions about our products and services, get in touch with your local Nynas contact. Besides top quality oils, we offer a wide range of services, including rapid delivery worldwide, training, seminars and much more. All you have to do is ask.

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Sales Executive

Maria Jose Municio

Maria Jose Municio

Sales Executive

 Marcela Tocelis

Marcela Tocelis

Sales Manager / Acting General Manager

 Lina Maria Zuluaga

Lina Maria Zuluaga

Sales Executive

 Martin Vergara

Martin Vergara

Customer Service Executive

 Juan Pablo Pace

Juan Pablo Pace

Customer Service Coordinator

 Paul Bester

Paul Bester

Channel Manager CEETMEIA

 Sameen Kadli

Sameen Kadli

Customer Service Executive

 Sibala Libish Kumar

Sibala Libish Kumar

Customer Service Executive

 Ovidiu Nan

Ovidiu Nan

General Manager

Sabine Langmuller

Sabine Langmuller

Customer Service Coordinator

David Barnett

David Barnett

Sales Manager

 Melissa Hill

Melissa Hill

Sales Representative

 Samantha Moodley

Samantha Moodley

Customer Service Executive

Lee Anne Williams

Lee Anne Williams

Customer Service Coordinator

David Barnett

David Barnett

Sales Manager

 Melissa Hill

Melissa Hill

Sales Representative

 Samantha Moodley

Samantha Moodley

Customer Service Executive

Lee Anne Williams

Lee Anne Williams

Customer Service Coordinator

 Paul Bester

Paul Bester

Channel Manager CEETMEIA

 Sameen Kadli

Sameen Kadli

Customer Service Executive

 Sibala Libish Kumar

Sibala Libish Kumar

Customer Service Executive

 Abigail Waller

Abigail Waller

General Manager / Sales Manager

Farhana Mitha

Farhana Mitha

Sales Executive

David Barnett

David Barnett

Sales Manager

 Melissa Hill

Melissa Hill

Sales Representative

 Samantha Moodley

Samantha Moodley

Customer Service Executive

Lee Anne Williams

Lee Anne Williams

Customer Service Coordinator

Marco Roncelli

Marco Roncelli

Sales Executive

 Ilenia Bellotti

Ilenia Bellotti

Customer Service Executive

Daniele Frustagli

General Manager

David Barnett

David Barnett

Sales Manager

 Melissa Hill

Melissa Hill

Sales Representative

 Samantha Moodley

Samantha Moodley

Customer Service Executive

Lee Anne Williams

Lee Anne Williams

Customer Service Coordinator

David Barnett

David Barnett

Sales Manager

 Melissa Hill

Melissa Hill

Sales Representative

 Samantha Moodley

Samantha Moodley

Customer Service Executive

Lee Anne Williams

Lee Anne Williams

Customer Service Coordinator

 Jason Wong

Jason Wong

APAC Regional Director

 Rio Nasution

Rio Nasution

General Manager / Sales Manager

Lawrence Teo

Lawrence Teo

Area Sales Manager Malaysia, Sri Lanka and Bangladesh

 Georgina Ng

Georgina Ng

Customer Service Executive

 Dawn Tay

Dawn Tay

Customer Service Executive

 Ovidiu Nan

Ovidiu Nan

General Manager

Sabine Langmuller

Sabine Langmuller

Customer Service Coordinator

 Ovidiu Nan

Ovidiu Nan

General Manager

Sabine Langmuller

Sabine Langmuller

Customer Service Coordinator

David Barnett

David Barnett

Sales Manager

 Melissa Hill

Melissa Hill

Sales Representative

 Samantha Moodley

Samantha Moodley

Customer Service Executive

Lee Anne Williams

Lee Anne Williams

Customer Service Coordinator

David Barnett

David Barnett

Sales Manager

 Melissa Hill

Melissa Hill

Sales Representative

 Samantha Moodley

Samantha Moodley

Customer Service Executive

Lee Anne Williams

Lee Anne Williams

Customer Service Coordinator

 Jason Wong

Jason Wong

APAC Regional Director

 Rio Nasution

Rio Nasution

General Manager / Sales Manager

Lawrence Teo

Lawrence Teo

Area Sales Manager Malaysia, Sri Lanka and Bangladesh

 Georgina Ng

Georgina Ng

Customer Service Executive

 Dawn Tay

Dawn Tay

Customer Service Executive

 Myriam Picado

Myriam Picado

General Manager / Sales Manager

 Juan Jiménez

Juan Jiménez

Sales Executive

 Jose Luis Maceda

Jose Luis Maceda

Customer Service Coordinator

 Gloria Villaverde Parrado

Gloria Villaverde Parrado

Customer Service Executive

Maria Jose Municio

Maria Jose Municio

Sales Executive

Maria Jose Municio

Maria Jose Municio

Sales Executive