Hot solution for hot melts

By boosting the compatibility of ingredients, naphthenic mineral oils are providing hot melt adhesive manufacturers with new and more flexible formulations

By boosting the compatibility of ingredients, naphthenic mineral oils are providing hot melt adhesive manufacturers with new and more flexible formulations.

For producers of hot melt adhesives, using metallocene-based polyolefins and resins derived from natural resources can offer significant cost-advantages. Naturally derived resins are typically less expensive to use as a tackifier than alternative hydrocarbon resins, partly because their production is based on renewable feedstock.

The challenge for manufacturers lies in incorporating these ingredients - which are typically incompatible - into hot melt formulations. The catalyst metallocene is being hailed as revolutionary for the polymer industry, but natural resins are not compatible with metallocene polyolefins (mPOs), which are also much easier to manufacture than traditional polymers.

This is where Nynas oils offer a solution. Naphthenic mineral oils show great promise as enablers of compatible mixtures, paving the way for more flexible hot melt formulations and a reduced risk exposure to feedstock shortages.

Studies carried out by Nynas demonstrate that oil with a high degree of polarity shows superior performance. Naturally based resins are polar materials, and in hot melts, the resin is typically dissolved in the oil.

However, for final formulations including polymers, peel performance testing of hot melt formulations reveals that the polarity of the oil is not the only determining factor for compatibility between natural resins and mPOs.

Investigating mineral oil, natural resin and mPO hot melt formulations

Rheology and cloud point studies show the oil/resin and resin/polymer compatibility for a variety of tackifiers and oils with different characteristics.

In Figure 1, rheological data indicates how the oil is able to render typically incompatible blends compatible.

Figure 2 illustrates that although hydrocarbon resin formulations deliver improved overall peel strength, results are comparable. Some alternative resin formulations display an improved peel strength on glass and polyethylene surfaces.

Further reading

Assisting an agent

Compatible with all sorts of rubber, naphthenic oil facilitates the dispersion of insoluble sulfur, the vulcanising agent used in the production of tyre rubber. Anna Eriksson explains how this helps improve the quality of the final rubber.

Naphthenic oil improves artificial fertilisers

The use of fertilisers around the world to boost agricultural production is both vital and constantly under critical scrutiny. Developing products that provide optimum benefits both economically and from an ecological viewpoint is an important challenge for the artificial fertiliser producer. Very small quantities of oil are employed in the production of fertilisers. The market demands optimal products and every link of the chain must be taken into consideration, including the properties of the oil being used.

Solubility the most important property – but difficult to measure

Solubility properties are crucial to process oils, particularly in relation to substances that need to be dissolved. Marika Joona, technical co-ordinator at Nynas R&D department, has investigated whether Hildebrand's solubility parameter can be used to describe the properties of process oils.

THERE IS MORE TO US THAN THIS

We are delighted you are interested in our products. If you have any questions about our products and services, get in touch with your local Nynas contact. Besides top quality oils, we offer a wide range of services, including rapid delivery worldwide, training, seminars and much more. All you have to do is ask.

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 Melissa Hill

Melissa Hill

Sales Representative

 Samantha Moodley

Samantha Moodley

Customer Service Executive

Lee Anne Williams

Lee Anne Williams

Customer Service Coordinator

David Barnett

David Barnett

Sales Manager

 Melissa Hill

Melissa Hill

Sales Representative

 Samantha Moodley

Samantha Moodley

Customer Service Executive

Lee Anne Williams

Lee Anne Williams

Customer Service Coordinator

 Paul Bester

Paul Bester

Channel Manager CEETMEIA

 Sameen Kadli

Sameen Kadli

Customer Service Executive

 Sibala Libish Kumar

Sibala Libish Kumar

Customer Service Executive

 Abigail Waller

Abigail Waller

General Manager / Sales Manager

Farhana Mitha

Farhana Mitha

Sales Executive

David Barnett

David Barnett

Sales Manager

 Melissa Hill

Melissa Hill

Sales Representative

 Samantha Moodley

Samantha Moodley

Customer Service Executive

Lee Anne Williams

Lee Anne Williams

Customer Service Coordinator

Marco Roncelli

Marco Roncelli

Sales Executive

 Ilenia Bellotti

Ilenia Bellotti

Customer Service Executive

Daniele Frustagli

General Manager

David Barnett

David Barnett

Sales Manager

 Melissa Hill

Melissa Hill

Sales Representative

 Samantha Moodley

Samantha Moodley

Customer Service Executive

Lee Anne Williams

Lee Anne Williams

Customer Service Coordinator

David Barnett

David Barnett

Sales Manager

 Melissa Hill

Melissa Hill

Sales Representative

 Samantha Moodley

Samantha Moodley

Customer Service Executive

Lee Anne Williams

Lee Anne Williams

Customer Service Coordinator

 Jason Wong

Jason Wong

APAC Regional Director

 Rio Nasution

Rio Nasution

General Manager / Sales Manager

Lawrence Teo

Lawrence Teo

Area Sales Manager Malaysia, Sri Lanka and Bangladesh

 Georgina Ng

Georgina Ng

Customer Service Executive

 Dawn Tay

Dawn Tay

Customer Service Executive

 Ovidiu Nan

Ovidiu Nan

General Manager

 Elisabeth Treiber

Elisabeth Treiber

Customer Service Executive

Sabine Langmuller

Sabine Langmuller

Customer Service Coordinator

 Ovidiu Nan

Ovidiu Nan

General Manager

 Elisabeth Treiber

Elisabeth Treiber

Customer Service Executive

Sabine Langmuller

Sabine Langmuller

Customer Service Coordinator

David Barnett

David Barnett

Sales Manager

 Melissa Hill

Melissa Hill

Sales Representative

 Samantha Moodley

Samantha Moodley

Customer Service Executive

Lee Anne Williams

Lee Anne Williams

Customer Service Coordinator

David Barnett

David Barnett

Sales Manager

 Melissa Hill

Melissa Hill

Sales Representative

 Samantha Moodley

Samantha Moodley

Customer Service Executive

Lee Anne Williams

Lee Anne Williams

Customer Service Coordinator

 Jason Wong

Jason Wong

APAC Regional Director

 Rio Nasution

Rio Nasution

General Manager / Sales Manager

Lawrence Teo

Lawrence Teo

Area Sales Manager Malaysia, Sri Lanka and Bangladesh